PSA Hydrogen Purification

Hydrogen gas is produced from a variety of different processes and is typically produced in an impure form. Typical processes include chemical synthesis by methane steam reforming, off-gassing from styrene or ethylene plants where hydrogen gas is produced as a by-product, and petrochemical applications such as hydrocracking or desulphurization. To use the hydrogen, a purification process is necessary to create purified hydrogen gas. Hydrogen pressure swing adsorption (H2PSA) is a process that capitalizes on the volatility of hydrogen and its overall lack of polarity and affinity for zeolites to purify contaminated gas streams.

Hydrogen generation typically involves the production of contaminants or side products that need to be removed. It includes compounds such as carbon monoxide, carbon dioxide, nitrogen, water and unreacted hydrocarbons. Hydrogen PSA takes advantage of the preferential adsorption of these components, eliminating them from the hydrogen stream to yield purified hydrogen.

Traditionally, Hydrogen PSA takes advantage of multiple sieve beds and is comprised of four phases: an adsorption phase, a depressurization phase, a regeneration phase and a repressurization phase. In the process, the impure stream of hydrogen is passed into the sieve bed where impurities are selectively adsorbed onto the molecular sieve under pressure. After the adsorption step is completed, regeneration is accomplished by depressurizing the bed which decreases the affinity of the impurities allowing them to be discarded. Further purification of the bed is achieved by purging with pure hydrogen to remove any remaining contaminants. The bed is again pressurized to repeat the adsorption process. The beds run in sync to allow continuous hydrogen generation.

Related Products


5A is the calcium-exchanged form of the type A zeolite molecular sieve and is primarily used for removing carbon dioxide, carbon monoxide, alcohols and other oxygenates, hydrogen sulfide, methyl and ethyl mercaptans, and others.



Type 13X offers enhanced adsorption properties and the ability to remove impurities too large to be adsorbed by the type A zeolites.


Calcium X

Calcium X (CaX) and Calcium LSX (CaLSX) molecular sieves are the calcium-exchanged forms of the 13X and LSX type zeolites.


Contact Zeochem to discuss your current or future hydrogen purification needs.

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